Supervisory Team: Richard C. Knighton PhD Supervisor: Richard C. Knighton Project Overview The aim of the project is to work on state-of-the-art heteropolymetallic architectures (polynuclear lanthanide clusters) in the area of luminescence, specifically two-photon processes – upconversion and downconversion (quantum cutting). Project Description We are searching for a highly motivated individual who is interested in a PhD in Inorganic Chemistry with Dr. Richard Knighton at the University of Southampton, starting in October 2024. Upconversion (UC) and downconversion (DC) are of paramount importance for the advancement of new quantum themes such as sensors for medicine and quantum computing. Research into the mechanism of UC and DC is relatively limited due to the media in which they operate – primarily solid-state or lanthanide nanoparticle materials. This project will investigate the properties of a novel class of heteropolymetallic lanthanide complexes for upconversion, permitting a deeper understanding of the mechanism of photon upconversion. This is an area of high priority and novelty, only five groups globally are working on molecular UC currently. Molecular DC has not currently been realised but represents a significant goal in future quantum technologies. The successful candidate will acquire proficiency in synthetic organic, coordination chemistry, photoluminescence spectroscopy, and single-crystal X-ray crystallography. The researcher will have full access to a suite of techniques via state-of-the-art facilities including NMR spectroscopy, IR, HPLC and Mass-Spectrometry, in addition to world-leading X-ray diffraction facilities. The candidate will also participate in group-meetings, school seminars and represent the group at national/international conferences. This will give them the opportunity to disseminate their research results with world-leaders in the area. The University of Southampton will give professional training and transferable skills through the PGR Development Hub which provides a suite of training courses and support services which promotes well-being and employability. Knighton et al, Angew. Chem. Int. Ed ., 2022, 61, e202113114 Knighton et al, J. Am. Chem. Soc. 2022, 144, 29, 13356–13365 Entry Requirements A very good undergraduate degree (at least a UK 2:1 honours degree, or its international equivalent). Closing date : 31 August 2024. Funding: We offer a range of funding opportunities for both UK and international students, including Bursaries and Scholarships. For more information please visit PhD Scholarships | Doctoral College | University of Southampton Funding will be awarded on a rolling basis, so apply early for the best opportunity to be considered. How To Apply Apply online by clicking the 'Apply' button, above. Select programme type (Research), 2024/25, Faculty of Engineering and Physical Sciences, next page select “PhD Chemistry (Full time)”. In Section 2 of the application form you should insert the name of the supervisor Richard C. Knighton Applications should include : Research Proposal Curriculum Vitae Two reference letters Degree Transcripts/Certificates to date For further information please contact: feps-pgr-applysoton.ac.uk The School of Chemistry is committed to promoting equality, diversity inclusivity as demonstrated by our Athena SWAN award. We welcome all applicants regardless of their gender, ethnicity, disability, sexual orientation or age, and will give full consideration to applicants seeking flexible working patterns and those who have taken a career break. The University has a generous maternity policy, onsite childcare facilities, and offers a range of benefits to help ensure employees’ well-being and work-life balance. The University of Southampton is committed to sustainability and has been awarded the Platinum EcoAward. We offer a range of funding opportunities for both UK and international students, including Bursaries and Scholarships